Issue 21, 2017
From the journal:

Chemical Communications

A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry†

Yinli Zhang,‡ab   Sheng Zhang,‡ac   Lin Sun,a   Qi Yang,a   Jing Han,a   Qing Wei,a   Gang Xie,a   Sanping Chen ORCID logo *a  and  Shengli Gaoa  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069, China
E-mail: sanpingchen@126.com

b Department of Chemistry, Xianyang Normal University, Xian'yang, Shaanxi 712000, P. R. China

c College of Chemistry and Chemical Engineering, Baoji University of Arts and Science, 1 Hi-Tech Avenue, Baoji, Shaanxi 721013, China

Abstract

It is a tremendous challenge to prepare solvent-free dense energetic metal–organic frameworks (EMOFs), hence also to improve their stability and energetic performance. In this study, based on in situ microcalorimetry, an interpenetrating EMOF without solvent molecules, [Cu(tztr)]n (1, H2tztr = 3-(tetrazol-5-yl)triazole) was obtained, possessing high stability (Tdec = 360 °C) and outstanding energetic properties (ΔHdet = 7.53 kcal cm−3, D = 8.429 km s−1, P = 40.02 GPa).

Graphical abstract: A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

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Article information

DOI
https://doi.org/10.1039/C7CC00545H
Article type
Communication
Submitted
20 Jan 2017
Accepted
16 Feb 2017
First published
17 Feb 2017

Chem. Commun., 2017,53, 3034-3037

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A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry

Y. Zhang, S. Zhang, L. Sun, Q. Yang, J. Han, Q. Wei, G. Xie, S. Chen and S. Gao, Chem. Commun., 2017, 53, 3034 DOI: 10.1039/C7CC00545H

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