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Issue 13, 2017
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The first nucleophilic C–H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes

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Abstract

The first nucleophilic perfluoroalkylation of arenes is based on the arene π-system activation via6-arene)tricarbonylchromium complexes. Perfluoroalkyl anions generated from Me3SiRF and a fluoride ion source [Me4N]F exclusively attack the arene ligand under mild conditions. The formed negatively charged analogs of Meisenheimer adducts readily undergo a one-pot oxidation to perfluoroalkyl arenes.

Graphical abstract: The first nucleophilic C–H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes

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Publication details

The article was received on 13 Dec 2016, accepted on 24 Jan 2017 and first published on 31 Jan 2017


Article type: Communication
DOI: 10.1039/C6CC09905J
Citation: Chem. Commun., 2017,53, 2146-2149

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    The first nucleophilic C–H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes

    N. V. Kirij, A. A. Filatov, G. Yu. Khrapach and Y. L. Yagupolskii, Chem. Commun., 2017, 53, 2146
    DOI: 10.1039/C6CC09905J

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