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Issue 25, 2016
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A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C–H alkylation of aliphatic nitriles

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Abstract

The efficient photosensitizing of decatungstate-based MOF with 1D channels was achieved via in situ synthesis under solvothermal conditions for light driven acceleration of β- or γ-site C–H alkylation of aliphatic nitriles. The high catalytic efficiency, excellent size selectivity, high stability and good recyclability of the photocatalyst offer an environmentally-friendly route for widening the scope of accessible nitriles in both laboratory and industry.

Graphical abstract: A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C–H alkylation of aliphatic nitriles

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Publication details

The article was received on 28 Jan 2016, accepted on 01 Mar 2016 and first published on 01 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC00862C
Citation: Chem. Commun., 2016,52, 4714-4717

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    A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C–H alkylation of aliphatic nitriles

    D. Shi, C. He, W. Sun, Z. Ming, C. Meng and C. Duan, Chem. Commun., 2016, 52, 4714
    DOI: 10.1039/C6CC00862C

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