[18]Annulene put into a new perspective

Dominik Lungerich; Alexey V. Nizovtsev; Frank W. Heinemann; Frank Hampel; Karsten Meyer; George Majetich; Paul v. R. Schleyer; Norbert Jux

doi:10.1039/C6CC01309K

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[18]Annulene put into a new perspective†‡

Dominik Lungerich,^a Alexey V. Nizovtsev,^b Frank W. Heinemann,^b Frank Hampel,^a Karsten Meyer,^b George Majetich,^c Paul v. R. Schleyer^c and Norbert Jux*^a

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* Corresponding authors

^a Department Chemie und Pharmazie & Interdisciplinary Center for Molecular Materials (ICMM), Organic Chemistry II, Friedrich-Alexander-Universität Erlangen–Nürnberg, Henkestraße 42, Erlangen, Germany
E-mail: norbert.jux@fau.de

^b Department Chemie und Pharmazie, Inorganic Chemistry, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, Erlangen, Germany

^c Department of Chemistry, University of Georgia, 140 Cedar St, Athens, GA 30602, USA

Abstract

New insights into [18]annulene were gained by looking more closely at its X-ray structure, revealing a close face-to-face stacking of 3.16 Å in a herringbone-like crystal packing. Hexadehydro[18]annulene was co-crystalized in a benzene matrix, demonstrating the stabilizing role of intercalated solvent molecules in solid annulenes.

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DOI: https://doi.org/10.1039/C6CC01309K
Article type: Communication
Submitted: 11 Feb 2016
Accepted: 02 Mar 2016
First published: 02 Mar 2016
This article is Open Access

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Chem. Commun., 2016,52, 4710-4713

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[18]Annulene put into a new perspective

D. Lungerich, A. V. Nizovtsev, F. W. Heinemann, F. Hampel, K. Meyer, G. Majetich, P. v. R. Schleyer and N. Jux, Chem. Commun., 2016, 52, 4710 DOI: 10.1039/C6CC01309K

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Chemical Communications

[18]Annulene put into a new perspective†‡

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[18]Annulene put into a new perspective

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