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Issue 67, 2015
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Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex

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Abstract

An unprecedented layered Pb-Kemp's triacid compound, Pb3[C6(CH3)3(CO2)3H6]2[DMF]3, has been synthesized. The material exhibits a selective CO2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb2+ and Cd2+ with Kemp's triacid reveals higher selectivity of Cd2+ over Pb2+.

Graphical abstract: Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex

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Publication details

The article was received on 30 Jun 2015, accepted on 15 Jul 2015 and first published on 15 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC05360A
Chem. Commun., 2015,51, 13166-13169

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    Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex

    S. B. Kim, D. W. Lee, S. Chang and K. M. Ok, Chem. Commun., 2015, 51, 13166
    DOI: 10.1039/C5CC05360A

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