Issue 34, 2015
From the journal:

Chemical Communications

Revisiting the assembly of amino ester-based benzene-1,3,5-tricarboxamides: chiral rods in solution†

Alaric Desmarchelier,ab   Matthieu Raynal,*ab   Patrick Brocorens,c   Nicolas Vanthuyned  and  Laurent Bouteiller*ab  

* Corresponding authors

a Sorbonne Université, UPMC Univ Paris 06, UMR 8232, IPCM, Chimie des Polymères, F-75005 Paris, France
E-mail: laurent.bouteiller@upmc.fr

b CNRS, UMR 8232, IPCM, Chimie des Polymères, F-75005 Paris, France

c Service de Chimie des Matériaux Nouveaux, Université de Mons/Materia Nova, Place du Parc, 20, B-7000 Mons, Belgium

d Aix Marseille Université, CNRS, iSm2, UMR 7313, 13397 Marseille cedex 20, France

Abstract

Some benzene-1,3,5-tricarboxamide (BTA) monomers derived from (L) α-amino esters self-assemble into long rods at millimolar concentrations, and display a strong chiral amplification effect. These rods are in competition with dimeric species.

Graphical abstract: Revisiting the assembly of amino ester-based benzene-1,3,5-tricarboxamides: chiral rods in solution

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Article information

DOI
https://doi.org/10.1039/C5CC01513H
Article type
Communication
Submitted
18 Feb 2015
Accepted
24 Mar 2015
First published
25 Mar 2015

Chem. Commun., 2015,51, 7397-7400

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Revisiting the assembly of amino ester-based benzene-1,3,5-tricarboxamides: chiral rods in solution

A. Desmarchelier, M. Raynal, P. Brocorens, N. Vanthuyne and L. Bouteiller, Chem. Commun., 2015, 51, 7397 DOI: 10.1039/C5CC01513H

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