Issue 34, 2015

Dibromoindium(iii) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

Abstract

[IPr·InBr2][SbF6] (2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has been synthesized and characterized in the solid state. This complex proved to be a very active catalyst for hydroarylations, transfer hydrogenations, and cycloisomerizations.

Graphical abstract: Dibromoindium(iii) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

Supplementary files

Article information

Article type
Communication
Submitted
26 Jan 2015
Accepted
24 Mar 2015
First published
24 Mar 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 7401-7404

Dibromoindium(III) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

B. Michelet, J. Colard-Itté, G. Thiery, R. Guillot, C. Bour and V. Gandon, Chem. Commun., 2015, 51, 7401 DOI: 10.1039/C5CC00740B

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