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Issue 34, 2015
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Dibromoindium(III) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

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Abstract

[IPr·InBr2][SbF6] (2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has been synthesized and characterized in the solid state. This complex proved to be a very active catalyst for hydroarylations, transfer hydrogenations, and cycloisomerizations.

Graphical abstract: Dibromoindium(iii) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

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Publication details

The article was received on 26 Jan 2015, accepted on 24 Mar 2015 and first published on 24 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC00740B
Citation: Chem. Commun., 2015,51, 7401-7404
  • Open access: Creative Commons BY-NC license
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    Dibromoindium(III) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

    B. Michelet, J. Colard-Itté, G. Thiery, R. Guillot, C. Bour and V. Gandon, Chem. Commun., 2015, 51, 7401
    DOI: 10.1039/C5CC00740B

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