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Issue 19, 2015
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Self-catalysis in thermal hysteresis during random-coil to helix-dimer transition of the sulfonamidohelicene tetramer

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Abstract

The sulfonamidohelicene tetramer changes its structure between a random-coil and a helix-dimer, by which molecular thermal hysteresis appears. Mixing experiments on helix-dimer and random-coil solutions and kinetic analysis show that the transition from the random-coil to the helix-dimer involves self-catalysis by the helix-dimer.

Graphical abstract: Self-catalysis in thermal hysteresis during random-coil to helix-dimer transition of the sulfonamidohelicene tetramer

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Publication details

The article was received on 30 Dec 2014, accepted on 28 Jan 2015 and first published on 29 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC10418H
Chem. Commun., 2015,51, 4040-4043

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    Self-catalysis in thermal hysteresis during random-coil to helix-dimer transition of the sulfonamidohelicene tetramer

    M. Shigeno, Y. Kushida and M. Yamaguchi, Chem. Commun., 2015, 51, 4040
    DOI: 10.1039/C4CC10418H

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