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Issue 95, 2014
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Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

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Abstract

Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF-1 is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.

Graphical abstract: Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

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Supplementary files

Article information


Submitted
28 Sep 2014
Accepted
13 Oct 2014
First published
13 Oct 2014

Chem. Commun., 2014,50, 14949-14952
Article type
Communication

Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

J. Dong, Y. Liu and Y. Cui, Chem. Commun., 2014, 50, 14949
DOI: 10.1039/C4CC07648F

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