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Issue 91, 2014
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One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis

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Abstract

We report herein the first photoredox-catalyzed intermolecular aryl- and heteroaryltrifluoromethylation of alkenes. Under the optimized conditions using Umemoto's reagent as a CF3 source, a wide range of styrenes can be readily difunctionalized, affording the corresponding trifluoromethylated adducts in up to 99% yield.

Graphical abstract: One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis

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Article information


Submitted
07 Sep 2014
Accepted
25 Sep 2014
First published
25 Sep 2014

Chem. Commun., 2014,50, 14197-14200
Article type
Communication
Author version available

One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis

A. Carboni, G. Dagousset, E. Magnier and G. Masson, Chem. Commun., 2014, 50, 14197
DOI: 10.1039/C4CC07066F

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