Issue 94, 2014
From the journal:

Chemical Communications

Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions†

Linfeng Xiong,a   Hui Zhang,a   Aiqing Zhong,a   Zidong Hea  and  Kun Huang*a  

* Corresponding authors

a Department of Chemistry, East China Normal University, Shanghai, P. R. China
E-mail: khuang@chem.ecnu.edu.cn

Abstract

We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.

Graphical abstract: Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

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Article information

DOI
https://doi.org/10.1039/C4CC06573E
Article type
Communication
Submitted
21 Aug 2014
Accepted
06 Oct 2014
First published
07 Oct 2014

Chem. Commun., 2014,50, 14778-14781

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Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

L. Xiong, H. Zhang, A. Zhong, Z. He and K. Huang, Chem. Commun., 2014, 50, 14778 DOI: 10.1039/C4CC06573E

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