Issue 85, 2014
From the journal:

Chemical Communications

Mn(iii)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines†

Jia-Jia Cao,a   Xiang Wang,a   Shun-Yi Wang*a  and  Shun-Jun Ji*a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
E-mail: shunyi@suda.edu.cn, shunjun@suda.edu.cn
Fax: +86-512-65880307
Tel: +86-512-65880307

Abstract

Mn(III)-mediated reactions of 2-isocyanobiaryls with 1,3-dicarbonyl compounds were described for the construction of 6-alkylated and 6-monofluoro-alkylated phenanthridines in moderate to good yields. The reaction involves formation of two new C–C bonds and one C–C bond cleavage.

Graphical abstract: Mn(iii)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

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Article information

DOI
https://doi.org/10.1039/C4CC05324A
Article type
Communication
Submitted
10 Jul 2014
Accepted
24 Aug 2014
First published
01 Sep 2014

Chem. Commun., 2014,50, 12892-12895

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Mn(III)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

J. Cao, X. Wang, S. Wang and S. Ji, Chem. Commun., 2014, 50, 12892 DOI: 10.1039/C4CC05324A

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