SCHEDULED MAINTENANCE
Carbon-centered radicals of alcohols commonly used as hydroxyl radical scavengers (MeOH, EtOH, i-PrOH and t-BuOH) add reversibly to histidine with equilibrium constants up to 3 × 103 M−1 and rate constants on the order of 109 M−1 s−1. Similar equilibria may compromise determinations of one-electron (radical) electrode potentials.
T. Nauser and A. Carreras, Chem. Commun., 2014, 50, 14349 DOI: 10.1039/C4CC05316H
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