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Issue 70, 2014
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Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

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Abstract

A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve either as a neutral [(dpp-bian)Ga:] or an anionic [(dpp-bian)Ga:] two-electron donor depending on the electronic state of the transition metal.

Graphical abstract: Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

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Supplementary files

Article information


Submitted
26 May 2014
Accepted
11 Jul 2014
First published
14 Jul 2014

Chem. Commun., 2014,50, 10108-10111
Article type
Communication
Author version available

Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

I. L. Fedushkin, V. G. Sokolov, A. V. Piskunov, V. M. Makarov, E. V. Baranov and G. A. Abakumov, Chem. Commun., 2014, 50, 10108
DOI: 10.1039/C4CC04019H

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