SCHEDULED MAINTENANCE
An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides has been reported, giving α,β-disubstituted enamides in high yields with excellent regio- and stereoselectivity. A possible mechanism involving the palladium carbene intermediate has been proposed to account for the unusual trans-addition.
Y. Yang, L. Wang, J. Zhang, Y. Jin and G. Zhu, Chem. Commun., 2014, 50, 2347 DOI: 10.1039/C3CC49069F
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