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Issue 39, 2014

High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds

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Abstract

A high density monolayer of diisocyanide on gold surface was utilized as a platform of supported Rh catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds. The catalyst exhibited high turnover numbers in a range of 50 000 to 150 000 per Rh atom and showed steady catalyst performance over six recycle usages.

Graphical abstract: High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds

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Article information


Submitted
25 Oct 2013
Accepted
03 Mar 2014
First published
04 Mar 2014

This article is Open Access

Chem. Commun., 2014,50, 5046-5048
Article type
Communication

High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds

S. Jagtap, Y. Kaji, A. Fukuoka and K. Hara, Chem. Commun., 2014, 50, 5046 DOI: 10.1039/C3CC48181F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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