Spin crossover complexes based on either iron(II) or iron(III) give a colorimetric response upon self-assembly with barbituric acids. They can be used as visible sensors for these narcotics, selectively detecting barbiturates in the presence of other biologically-relevant hydrogen bonding species.
M. C. Young, E. Liew and R. J. Hooley, Chem. Commun., 2014, 50, 5043 DOI: 10.1039/C4CC01805B
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