Issue 4, 2014
From the journal:

Chemical Communications

An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand†

Peng Cui,a   Thomas P. Spaniol,a   Laurent Maron*b  and  Jun Okuda*a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de
Fax: +49 241 8092644

b Université de Toulouse et CNRS, NSA, UPS, CNRS, UMR 5215 LPCNO, 135 avenue de Rangueil, 31077 Toulouse, France
E-mail: Laurent.maron@irsamc.ups-tlse.fr
Fax: +33 5-6155-9697

Abstract

A scandium hydride supported by a (NNNN)-type macrocycle consists of a trinuclear cation and a trinuclear anion. The anion shows significantly higher reactivity.

Graphical abstract: An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand

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Article information

DOI
https://doi.org/10.1039/C3CC47805J
Article type
Communication
Submitted
10 Oct 2013
Accepted
31 Oct 2013
First published
01 Nov 2013

Chem. Commun., 2014,50, 424-426

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An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand

P. Cui, T. P. Spaniol, L. Maron and J. Okuda, Chem. Commun., 2014, 50, 424 DOI: 10.1039/C3CC47805J

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