Issue 26, 2012
From the journal:

Chemical Communications

Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds†

Rajarshi Samanta,‡a   Jonas Lategahn‡ab  and  Andrey P. Antonchick*a  

* Corresponding authors

a Max-Planck Institute of Molecular Physiology, Otto-Hahn Strasse 11, Dortmund 44227, Germany
E-mail: andrey.antonchick@mpi-dortmund.mpg.de

b TU Dortmund, Faculty of Chemistry, Otto-Hahn-Strasse 6, Dortmund 44227, Germany

Abstract

A new atom-economical process of direct oxidative intermolecular functionalization of aniline derivatives by simple arenes was developed. The products were formed in a highly regioselective manner under metal-free conditions at ambient temperature.

Graphical abstract: Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds

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Article information

DOI
https://doi.org/10.1039/C2CC30324H
Article type
Communication
Submitted
05 Dec 2011
Accepted
25 Jan 2012
First published
25 Jan 2012

Chem. Commun., 2012,48, 3194-3196

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Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C–C and C–N bonds

R. Samanta, J. Lategahn and A. P. Antonchick, Chem. Commun., 2012, 48, 3194 DOI: 10.1039/C2CC30324H

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