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Issue 10, 2012

Ortho-methylated tribenzotriquinacenes—paving the way to curved carbon networks

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Abstract

The synthesis of sterically crowded tribenzotriquinacenes with complete and partial methylation of the ortho-positions has been achieved using the double cyclodehydration strategy. This leads to a twisted tribenzotriquinacene core and enables further functionalization for the future synthesis of curved model compounds for defective carbon networks.

Graphical abstract: Ortho-methylated tribenzotriquinacenes—paving the way to curved carbon networks

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Article information


Submitted
30 Jul 2011
Accepted
21 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2012,48, 1502-1504
Article type
Communication

Ortho-methylated tribenzotriquinacenes—paving the way to curved carbon networks

Y. Kirchwehm, A. Damme, T. Kupfer, H. Braunschweig and A. Krueger, Chem. Commun., 2012, 48, 1502 DOI: 10.1039/C1CC14703J

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