Issue 10, 2012
From the journal:

Chemical Communications

Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?†

Iurii L. Malaestean,a   Arkady Ellern,b   Svetlana Bacaa  and  Paul Kögerler*a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, 52070 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de
Fax: +49-241-80-92642
Tel: +49-241-80-93642

b Ames Laboratory, Iowa State University, Ames, USA

Abstract

The mixed-valent cerium(III/IV) oxide clusters {Ce10} and {Ce22}, derived from condensation reactions of cerium carboxylate coordination polymers, exhibit molecular growth tendencies similar to those of ‘classical’ group V and VI polyoxometalates, but with increasing nuclearity approach the structure of the parental oxide, CeO2.

Graphical abstract: Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?

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Article information

DOI
https://doi.org/10.1039/C1CC14725K
Article type
Communication
Submitted
31 Jul 2011
Accepted
20 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2012,48, 1499-1501

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Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?

I. L. Malaestean, A. Ellern, S. Baca and P. Kögerler, Chem. Commun., 2012, 48, 1499 DOI: 10.1039/C1CC14725K

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