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Issue 10, 2012
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Rhodium-catalyzed redox allylation reactions of ketones

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Abstract

Ketones react with allyl acetate to generate tertiary homoallylic alcohols in the presence of a rhodium catalyst and bis(pinacolato)diboron. A range of substrates, including aryl, alkyl and cyclic ketones react smoothly under these conditions. Diastereoselective allylation reactions of functionalized ketones such as pregnenolone acetate are also reported.

Graphical abstract: Rhodium-catalyzed redox allylation reactions of ketones

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Supplementary files

Article information


Submitted
30 Jul 2011
Accepted
20 Sep 2011
First published
10 Oct 2011

Chem. Commun., 2012,48, 1496-1498
Article type
Communication

Rhodium-catalyzed redox allylation reactions of ketones

F. J. Williams, R. E. Grote and E. R. Jarvo, Chem. Commun., 2012, 48, 1496 DOI: 10.1039/C1CC14691B

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