Issue 42, 2011
From the journal:

Chemical Communications

Determination of concentration and enantiomeric excess of amines and amino alcohols with a chiral nickel(ii) complex†

Xuan He,a   Qi Zhang,a   Xiaohua Liu,a   Lili Lina  and  Xiaoming Feng*a  

* Corresponding authors

a Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, China
E-mail: xmfeng@scu.edu.cn
Fax: (+86) 28-8541-8249

Abstract

A chiral N,N′-dioxide–Ni(II) complex was found to exhibit highly enantioselective fluorescent recognition of chiral amines and amino alcohols. It can be used to determine their concentration and ee value. Using a 96-well plate, high-throughput screening for enantiomer discrimination was accomplished.

Graphical abstract: Determination of concentration and enantiomeric excess of amines and amino alcohols with a chiral nickel(ii) complex

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Article information

DOI
https://doi.org/10.1039/C1CC14660B
Article type
Communication
Submitted
29 Jul 2011
Accepted
26 Aug 2011
First published
08 Sep 2011

Chem. Commun., 2011,47, 11641-11643

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Determination of concentration and enantiomeric excess of amines and amino alcohols with a chiral nickel(II) complex

X. He, Q. Zhang, X. Liu, L. Lin and X. Feng, Chem. Commun., 2011, 47, 11641 DOI: 10.1039/C1CC14660B

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