Issue 42, 2011
From the journal:

Chemical Communications

Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane†

Gastón A. Crespo,a   Günter Mistlbergera  and  Eric Bakker*a  

* Corresponding authors

a Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
E-mail: eric.bakker@unige.ch

Abstract

We demonstrate here for the first time the detection of electrogenerated chemiluminescence (ECL) upon selective, electrochemically triggered tris(2,2′-bipyridyl)ruthenium(II) (Ru(bpy)32+) transport across a supported liquid membrane doped with a lipophilic cation-exchanger. This approach allows one to separate the location of ECL generation from the sample compartment, thereby avoiding the contamination of the sample with compounds necessary for ECL.

Graphical abstract: Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane

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Article information

DOI
https://doi.org/10.1039/C1CC14822B
Article type
Communication
Submitted
04 Aug 2011
Accepted
13 Sep 2011
First published
28 Sep 2011

Chem. Commun., 2011,47, 11644-11646

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Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane

G. A. Crespo, G. Mistlberger and E. Bakker, Chem. Commun., 2011, 47, 11644 DOI: 10.1039/C1CC14822B

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