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Issue 33, 2011
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Catalytic intermolecular allyl–allyl cross-couplings between alcohols and boronates

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Abstract

We developed catalytic intermolecular C(sp3)–C(sp3) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.

Graphical abstract: Catalytic intermolecular allyl–allyl cross-couplings between alcohols and boronates

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Submitted
06 Jun 2011
Accepted
07 Jul 2011
First published
22 Jul 2011

Chem. Commun., 2011,47, 9456-9458
Article type
Communication

Catalytic intermolecular allylallyl cross-couplings between alcohols and boronates

A. Jiménez-Aquino, E. Ferrer Flegeau, U. Schneider and S. Kobayashi, Chem. Commun., 2011, 47, 9456
DOI: 10.1039/C1CC13348A

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