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Issue 38, 2010
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Dioxygenactivation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

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Abstract

The isolation, structural chracterisation and electronic structure of a formally mixed-valent Rh(−I)-Rh(III) complex is described, along with its reaction with dioxygen leading to double arene hydroxylation of the coordinated ligands.

Graphical abstract: Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

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Article information


Submitted
14 Jun 2010
Accepted
17 Aug 2010
First published
31 Aug 2010

Chem. Commun., 2010,46, 7124-7126
Article type
Communication

Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

N. D. Paul, T. Krämer, J. E. McGrady and S. Goswami, Chem. Commun., 2010, 46, 7124
DOI: 10.1039/C0CC01880E

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