Issue 38, 2010
From the journal:

Chemical Communications

Dioxygenactivation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands†

Nanda D. Paul,a   Tobias Krämer,b   John E. McGrady*b  and  Sreebrata Goswami*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata 700 032, India
E-mail: icsg@iacs.res.in
Fax: +91-33-2473 2805
Tel: +91-33-2473 4971

b Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK

Abstract

The isolation, structural chracterisation and electronic structure of a formally mixed-valent Rh(−I)-Rh(III) complex is described, along with its reaction with dioxygen leading to double arene hydroxylation of the coordinated ligands.

Graphical abstract: Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

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Article information

DOI
https://doi.org/10.1039/C0CC01880E
Article type
Communication
Submitted
14 Jun 2010
Accepted
17 Aug 2010
First published
31 Aug 2010

Chem. Commun., 2010,46, 7124-7126

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Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

N. D. Paul, T. Krämer, J. E. McGrady and S. Goswami, Chem. Commun., 2010, 46, 7124 DOI: 10.1039/C0CC01880E

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