Issue 7, 2010
From the journal:

Chemical Communications

Clean synthesis of triarylamines: Buchwald–Hartwig reaction in water with amphiphilic resin-supported palladium complexes†

Yoshinori Hirai‡a  and  Yasuhiro Uozumi*a  

* Corresponding authors

a Institute for Molecular Science, Myodaiji, Okazaki, Aichi 444-8787, Japan
E-mail: uo@ims.ac.jp
Fax: +81 564 95 5574
Tel: +81 564 59 5571

Abstract

Catalytic aromatic amination was achieved in water under heterogeneous conditions by the use of palladium complexes anchored to the amphiphilic PS-PEG resin with little palladium leaching to provide a green and clean (metal-uncontaminated) protocol for the preparation of triarylamines, including the optoelectronically active N,N,N′,N′-tetraaryl-1,1′-biphenyl-4,4′-diamines (TPDs).

Graphical abstract: Clean synthesis of triarylamines: Buchwald–Hartwig reaction in water with amphiphilic resin-supported palladium complexes

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Article information

DOI
https://doi.org/10.1039/B918424D
Article type
Communication
Submitted
07 Sep 2009
Accepted
03 Dec 2009
First published
23 Dec 2009

Chem. Commun., 2010,46, 1103-1105

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Clean synthesis of triarylamines: Buchwald–Hartwig reaction in water with amphiphilic resin-supported palladium complexes

Y. Hirai and Y. Uozumi, Chem. Commun., 2010, 46, 1103 DOI: 10.1039/B918424D

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