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Issue 7, 2010
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Clean synthesis of triarylamines: Buchwald–Hartwig reaction in water with amphiphilic resin-supported palladium complexes

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Abstract

Catalytic aromatic amination was achieved in water under heterogeneous conditions by the use of palladium complexes anchored to the amphiphilic PS-PEG resin with little palladium leaching to provide a green and clean (metal-uncontaminated) protocol for the preparation of triarylamines, including the optoelectronically active N,N,N′,N′-tetraaryl-1,1′-biphenyl-4,4′-diamines (TPDs).

Graphical abstract: Clean synthesis of triarylamines: Buchwald–Hartwig reaction in water with amphiphilic resin-supported palladium complexes

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Publication details

The article was received on 07 Sep 2009, accepted on 03 Dec 2009 and first published on 23 Dec 2009


Article type: Communication
DOI: 10.1039/B918424D
Chem. Commun., 2010,46, 1103-1105

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    Clean synthesis of triarylamines: Buchwald–Hartwig reaction in water with amphiphilic resin-supported palladium complexes

    Y. Hirai and Y. Uozumi, Chem. Commun., 2010, 46, 1103
    DOI: 10.1039/B918424D

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