Issue 7, 2010
From the journal:

Chemical Communications

A rutile-type porous zinc(ii)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis†

Teng-Biao Liao,‡a   Yun Ling,‡a   Zhen-Xia Chen,a   Ya-Ming Zhou*a  and  Lin-Hong Wenga  

* Corresponding authors

a Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China
E-mail: ymzhou@fudan.edu.cn
Fax: +86 21 65643925
Tel: +86 21 65642261

Abstract

The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal–organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selective properties.

Graphical abstract: A rutile-type porous zinc(ii)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis

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Article information

DOI
https://doi.org/10.1039/B917987A
Article type
Communication
Submitted
02 Sep 2009
Accepted
02 Dec 2009
First published
23 Dec 2009

Chem. Commun., 2010,46, 1100-1102

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A rutile-type porous zinc(II)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis

T. Liao, Y. Ling, Z. Chen, Y. Zhou and L. Weng, Chem. Commun., 2010, 46, 1100 DOI: 10.1039/B917987A

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