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Issue 41, 2008
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Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

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Abstract

Diastereopure troposRh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

Graphical abstract: Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

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Publication details

The article was received on 09 Jun 2008, accepted on 14 Aug 2008 and first published on 30 Sep 2008


Article type: Communication
DOI: 10.1039/B809683J
Citation: Chem. Commun., 2008,0, 5095-5097

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    Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

    K. Aikawa, Y. Takabayashi, S. Kawauchi and K. Mikami, Chem. Commun., 2008, 0, 5095
    DOI: 10.1039/B809683J

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