Issue 19, 2008
From the journal:

Chemical Communications

Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex†

Bao Li,a   Jun Tao,*a   Hao-Ling Sun,b   Osamu Sato,*b   Rong-Bin Huanga  and  Lan-Sun Zhenga  

* Corresponding authors

a State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen 361005, People’s Republic of China
E-mail: taojun@xmu.edu.cn

b Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan
E-mail: sato@cm.kyushu-u.ac.jp

Abstract

A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

Graphical abstract: Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

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Article information

DOI
https://doi.org/10.1039/B801171K
Article type
Communication
Submitted
22 Jan 2008
Accepted
19 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 2269-2271

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Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

B. Li, J. Tao, H. Sun, O. Sato, R. Huang and L. Zheng, Chem. Commun., 2008, 2269 DOI: 10.1039/B801171K

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