Issue 19, 2008
From the journal:

Chemical Communications

Structural diversity of 1,2,4-diazaphospholide complexes with alkali metals†‡

Li Wan,a   Chengfu Pi,a   Lan Zhang,a   Wenjun Zheng,*a   Linhong Weng,a   Zhenxia Chena  and  Yong Zhangb  

* Corresponding authors

a Department of Chemistry, Fudan University, Handan Road 220, Shanghai 200433, China
E-mail: wjzheng@fudan.edu.cn
Fax: +86 021-65642408
Tel: +86 021-65642408

b College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China

Abstract

Treatment of H[3,5-Ph2dp] (Hdp = 1H-1,2,4-diazaphosphole) with nBuLi or KH, or the reaction of K[3,5-tBu2dp] with an excess amount of O2, afforded the dimeric species [(η2,η1-3,5-Ph2dp)Li(THF)2]2 and the polymeric complexes [(η2:η4-3,5-Ph2dp)K(Et2O)2]n, and [{(η2:η5-3,5-tBu2dp)K(THF)}{η2(N,N)-η3(O,P,O)-3,5-tBu2dp-(O,O)O2K}]n, respectively.

Graphical abstract: Structural diversity of 1,2,4-diazaphospholide complexes with alkali metals

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B800222C
Article type
Communication
Submitted
08 Jan 2008
Accepted
22 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 2266-2268

Permissions

Request permissions

Structural diversity of 1,2,4-diazaphospholide complexes with alkali metals

L. Wan, C. Pi, L. Zhang, W. Zheng, L. Weng, Z. Chen and Y. Zhang, Chem. Commun., 2008, 2266 DOI: 10.1039/B800222C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements