Issue 19, 2008

Structural diversity of 1,2,4-diazaphospholide complexes with alkali metals

Abstract

Treatment of H[3,5-Ph2dp] (Hdp = 1H-1,2,4-diazaphosphole) with nBuLi or KH, or the reaction of K[3,5-tBu2dp] with an excess amount of O2, afforded the dimeric species [(η21-3,5-Ph2dp)Li(THF)2]2 and the polymeric complexes [(η24-3,5-Ph2dp)K(Et2O)2]n, and [{(η25-3,5-tBu2dp)K(THF)}{η2(N,N)-η3(O,P,O)-3,5-tBu2dp-(O,O)O2K}]n, respectively.

Graphical abstract: Structural diversity of 1,2,4-diazaphospholide complexes with alkali metals

Supplementary files

Article information

Article type
Communication
Submitted
08 Jan 2008
Accepted
22 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 2266-2268

Structural diversity of 1,2,4-diazaphospholide complexes with alkali metals

L. Wan, C. Pi, L. Zhang, W. Zheng, L. Weng, Z. Chen and Y. Zhang, Chem. Commun., 2008, 2266 DOI: 10.1039/B800222C

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