Issue 48, 2007

The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Abstract

The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP)6]Cl6ยท19CHCl3 comprising [P3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

Graphical abstract: The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Supplementary files

Article information

Article type
Communication
Submitted
10 Sep 2007
Accepted
28 Sep 2007
First published
10 Oct 2007

Chem. Commun., 2007, 5152-5154

The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

R. Boomishankar, J. Ledger, J. Guilbaud, N. L. Campbell, J. Bacsa, R. Bonar-Law, Y. Z. Khimyak and A. Steiner, Chem. Commun., 2007, 5152 DOI: 10.1039/B713847D

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