Issue 35, 2005

Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicity-induced spontaneous resolution

Abstract

In the pair of helical conformational polymorphs of the coordination polymer {[AgL](CF3SO3)} (L = 2-pyridinyl-3-pyridinylmethanone), the 21 helices of opposite chirality in one supramolecular isomer are stacked alternately to form a racemate, while the 41 helices in the other are assembled homochirally by inter-chain argentophilic interaction to generate a conglomerate.

Graphical abstract: Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicity-induced spontaneous resolution

Supplementary files

Article information

Article type
Communication
Submitted
25 May 2005
Accepted
14 Jul 2005
First published
09 Aug 2005

Chem. Commun., 2005, 4417-4419

Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicity-induced spontaneous resolution

X. Chen, M. Du and T. C. W. Mak, Chem. Commun., 2005, 4417 DOI: 10.1039/B507363D

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