Issue 35, 2005
From the journal:

Chemical Communications

Crystal engineering of nonporous organic solids for methane sorption†

Praveen K. Thallapally,a   Trevor B. Wirsig,a   Leonard J. Barbour*b  and  Jerry L. Atwood*a  

* Corresponding authors

a Department of Chemistry, University of Missouri-Columbia, Columbia, MO, USA
E-mail: atwoodj@missouri.edu
Fax: +1 573 882 2754
Tel: +1 573 882 2730

b Department of Chemistry, University of Stellenbosch, Stellenbosch, South Africa
E-mail: ljb@sun.ac.za
Fax: +27 21 808 3849
Tel: +27 21 808 3335

Abstract

The low density polymorph of the well-known host p-tert-butylcalix[4]arene absorbs more methane than p-tert-pentylcalix[4]arene at room temperature and 1 atm pressure, but the order of absorption is reversed at 38 atm with p-tert-pentylcalix[4]arene absorbing more.

Graphical abstract: Crystal engineering of nonporous organic solids for methane sorption

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Article information

DOI
https://doi.org/10.1039/B507406A
Article type
Communication
Submitted
26 May 2005
Accepted
01 Jul 2005
First published
29 Jul 2005

Chem. Commun., 2005, 4420-4422

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Crystal engineering of nonporous organic solids for methane sorption

P. K. Thallapally, T. B. Wirsig, L. J. Barbour and J. L. Atwood, Chem. Commun., 2005, 4420 DOI: 10.1039/B507406A

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