Issue 17, 2003
From the journal:

Chemical Communications

A building block approach to the synthesis of organic–inorganic oxide materials: the hydrothermal synthesis and network structure of [{Ni4(tpypyz)3}{Mo5O†15(O3PCH2CH2PO3)}2]·23H2O (tpypyz = tetra-2-pyridylpyrazine)

Eric Burkholder,a   Vladimir Golub,b   Charles J. O'Connorb  and  Jon Zubieta*a  

* Corresponding authors

a Department of Chemistry, Syracuse University, Syracuse, NY 13244, USA
E-mail: jazubiet@syr.edu

b Department of Chemistry, University of New Orleans, New Orleans, LA, USA

Abstract

The hydrothermal reaction of MoO3, [Ni(CH3CO2)2]·4H2O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [{Ni4(tpypyz)3}{Mo5O15(O3PCH2CH2PO3)}2]·23H2O (1·23H2O), constructed from {Mo5O15(O3PCH2CH2PO3)}4− clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal–ligand subunit {Ni4(tpypyz)3}8+.

Graphical abstract: A building block approach to the synthesis of organic–inorganic oxide materials: the hydrothermal synthesis and network structure of [{Ni4(tpypyz)3}{Mo5O15(O3PCH2CH2PO3)}2]·23H2O (tpypyz = tetra-2-pyridylpyrazine)

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Article information

DOI
https://doi.org/10.1039/B303659F
Article type
Communication
Submitted
01 Apr 2003
Accepted
15 Jul 2003
First published
24 Jul 2003

Chem. Commun., 2003, 2128-2129

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A building block approach to the synthesis of organic–inorganic oxide materials: the hydrothermal synthesis and network structure of [{Ni4(tpypyz)3}{Mo5O15(O3PCH2CH2PO3)}2]·23H2O (tpypyz = tetra-2-pyridylpyrazine)

E. Burkholder, V. Golub, C. J. O'Connor and J. Zubieta, Chem. Commun., 2003, 2128 DOI: 10.1039/B303659F

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