Issue 6, 2002
From the journal:

Chemical Communications

Reductive complexation of cycloheptatrienes by iron pentacarbonyl and catalytic sodium borohydride

Yoann Coquerela  and  Jean-Pierre Deprésa  

a LEDSS, Université Joseph Fourier, Bâtiment Chimie Recherche, 301 rue de la Chimie, BP 53, Grenoble Cedex 9, France
E-mail: jean-pierre.depres@ujf-grenoble.fr

Abstract

Fe(CO)5 and a catalytic amount of sodium borohydride react with cycloheptatrienes in protic solvents to yield the corresponding tricarbonyl(η4-1,3-diene)iron complexes in a one-pot procedure, which has been found to be particularly efficient for the synthesis of the useful tricarbonyl(cycloheptadiene)iron complex.

Graphical abstract: Reductive complexation of cycloheptatrienes by iron pentacarbonyl and catalytic sodium borohydride

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Article information

DOI
https://doi.org/10.1039/B111618P
Article type
Communication
Submitted
20 Dec 2001
Accepted
11 Feb 2002
First published
27 Feb 2002

Chem. Commun., 2002, 658-659

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Reductive complexation of cycloheptatrienes by iron pentacarbonyl and catalytic sodium borohydride

Y. Coquerel and J. Deprés, Chem. Commun., 2002, 658 DOI: 10.1039/B111618P

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