Synthesis, structure, and reactions of a nitroxyl complex of iridium(iii), cis,trans-IrHCl2(NH![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif) O)(PPh3)2
O)(PPh3)2                                                    
                    Abstract
Reaction of Ir(NO)(PPh3)3 with anhydrous HCl results in addition of 2 equivalents of HCl with formal protonation of the nitrosyl ![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif) O)(PPh3)2.
O)(PPh3)2.
 
                



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        ![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif) O)(PPh3)2
O)(PPh3)2