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Issue 23, 2000
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Palladium-catalysed asymmetric [4 + 2] cycloaddition of vinylallene with 1,3-diene

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Abstract

A catalytic asymmetric [4 + 2] cycloaddition reaction of a vinylallene with buta-1,3-diene was developed in which a palladium complex modified by a ferrocene-derived chiral monophosphine ligand acted as a template transferring chirality to the product.

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Article information


Submitted
06 Sep 2000
Accepted
05 Oct 2000
First published
07 Nov 2000

Chem. Commun., 2000, 2293-2294
Article type
Communication

Palladium-catalysed asymmetric [4 + 2] cycloaddition of vinylallene with 1,3-diene

M. Murakami, R. Minamida, K. Itami, M. Sawamura and Y. Ito, Chem. Commun., 2000, 2293
DOI: 10.1039/B007781J

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