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Issue 22, 2000
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An approach to open-chain 1,5-stereocontrol using a silyl group

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Abstract

Nucleophilic attack by an ethylcuprate on the α,β-unsaturated ketone 3 takes place anti to the silyl group to give largely (96∶4) a single product 4, fragmentation of which removes the silyl group, and reveals a pair of stereogenic centres having an open-chain 1,5 relationship 9.

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Publication details

The article was received on 07 Aug 2000, accepted on 26 Sep 2000 and first published on 20 Oct 2000


Article type: Communication
DOI: 10.1039/B006515N
Chem. Commun., 2000, 2185-2186

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    An approach to open-chain 1,5-stereocontrol using a silyl group

    I. Fleming and C. Ramarao, Chem. Commun., 2000, 2185
    DOI: 10.1039/B006515N

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