The reaction of [BaI2(thf)5] with LiOBut in THF in the presence of hydroxide yields a volatile mixed alkali and alkaine earth metal cluster with an unusually low coordination number for the alkaline earth cation; due to the presence of the alkoxide groups, the cluster is volatile at temperatures below 200 °C.
Synthesis and crystal structure of [IBa(OBut)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium
K. M. Fromm, E. D. Gueneau and H. Goesmann, Chem. Commun., 2000, 2187 DOI: 10.1039/B005638N
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