Extension of a π-stacked N2S ligand to form bi- and tri-nuclear silver(i) complexesDedicated to Dr Charles R. Clark on the occasion of his 60th birthday.
Abstract
Reactions of tri- and penta-dentate thio-substituted oligopyridines with Ag(I) yielded two differently coded bi- and tri-nuclear structures containing strong intraligand π stacking of the heterocycles.