Rate constants for the reaction of cumylperoxyl radicals with Bu3SnH and (TMS)3SiH
Abstract
The rate constants for the reaction of a cumylperoxyl radical with Bu3SnH and (TMS)3SiH were determined at 72.5 °C to be 1600 and 66 M–1 s–1, respectively, by using inhibited hydrocarbon oxidation methodologies.