Issue 6, 1997
From the journal:

Chemical Communications

New reaction mode of the Horner–Wadsworth–Emmons reaction using Sn(OSO2CF3)2 and N-ethylpiperidine

Shigeki Sano,   Kenji Yokoyama,   Mari Fukushima,   Tetsuo Yagi  and  Yoshimitsu Nagao  

Abstract

Excellent Z or E selectivity is observed in the Horner–Wadsworth–Emmons reactions of methyl bis(trifluoroethyl)phosphonoacetate 2 with aryl alkyl ketones 3a–d or aldehydes 3f,g using Sn(OSO 2 CF 3 ) 2 in the presence of N-ethylpiperidine, which should have a different reaction mode to those using sodium hydride.

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Article information

DOI
https://doi.org/10.1039/A608495H
Article type
Paper

Chem. Commun., 1997, 559-560

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New reaction mode of the Horner–Wadsworth–Emmons reaction using Sn(OSO2CF3)2 and N-ethylpiperidine

S. Sano, K. Yokoyama, M. Fukushima, T. Yagi and Y. Nagao, Chem. Commun., 1997, 559 DOI: 10.1039/A608495H

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