SCHEDULED MAINTENANCE
(2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.
L. Jaquinod, C. Gros, M. M. Olmstead, M. Antolovich and K. M. Smith, Chem. Commun., 1996, 1475 DOI: 10.1039/CC9960001475
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
