Issue 7, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

The isolation and characterization of a new class of mixed-valence dirhenium alkylidyne complexes

Keng-Yu Shih,   Phillip E. Fanwick  and  Richard A. Walton  

Abstract

The structural identity of the novel mixed-valence dirhenium alkylidyne complexes [(L)ClRe(µ-Cl)(µ-CO)(µ-dppm)2Re([triple bond, length half m-dash]CCH2R)]Cl (dppm = Ph2PCH2PPh2; L = Co or xylNC; R. = Prn or Bun) formed viathe ring-opening reaction of the 3-metallafuran complexes [Re2(µ-Cl){µCOCH(R)CH}Cl2(L)(µ-dppm)2]PF6, is established by an X-ray structure determination of the derivative where L = xylNC and R = Prn.

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Article information

DOI
https://doi.org/10.1039/C39940000861
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 861-862

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The isolation and characterization of a new class of mixed-valence dirhenium alkylidyne complexes

K. Shih, P. E. Fanwick and R. A. Walton, J. Chem. Soc., Chem. Commun., 1994, 861 DOI: 10.1039/C39940000861

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