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Issue 7, 1994
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Novel allenylidene alkynyl and ammonia alkynyl metal complexes via selective synthesis of mono and bis alkynyl ruthenium(II) complexes; crystal structure of trans-[Ru(NH3)(C[triple bond, length half m-dash]CPh)(Ph2PCH2CH2PPh2)2]PF6

Abstract

The activation of terminal alkynes with cis-[RuCl2(Ph2PCH2CH2PPh2)2] leads either to mono alkynyl, via vinylidene complex, or to bis alkynyl ruthenium complexes that are the key precursors of trans-[Ru(NH3)(C[triple bond, length half m-dash]CR)-(Ph2PCH2CH2PPh2)2]PF6 and [(Ph2C[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]RuC[triple bond, length half m-dash]CPh)(Ph2PCH2CH2PPh2)2]PF6 derivatives.

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Article type: Paper
DOI: 10.1039/C39940000859
Citation: J. Chem. Soc., Chem. Commun., 1994,0, 859-860

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    Novel allenylidene alkynyl and ammonia alkynyl metal complexes via selective synthesis of mono and bis alkynyl ruthenium(II) complexes; crystal structure of trans-[Ru(NH3)(C[triple bond, length half m-dash]CPh)(Ph2PCH2CH2PPh2)2]PF6

    D. Touchard, C. Morice, V. Cadierno, P. Haquette, L. Toupet and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1994, 0, 859
    DOI: 10.1039/C39940000859

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