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Issue 5, 1994
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Iron(III)–copper(II) and manganese(III)–copper(II) promoted cyclizations: a new stereoselective approach towards α-methyl substituted penicillin derivatives

Abstract

The stereoselective synthesis of α-methyl substituted penicillin by FeIII–CuII and MnIII–CuII promoted cyclizations and its relationship with the Baldwin's INPS (isopenicillin N synthase) mechanistic hypothesis on the biosynthesis of penicillin is described.

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Article type: Paper
DOI: 10.1039/C39940000597
Citation: J. Chem. Soc., Chem. Commun., 1994,0, 597-598

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    Iron(III)–copper(II) and manganese(III)–copper(II) promoted cyclizations: a new stereoselective approach towards α-methyl substituted penicillin derivatives

    W. Cabri, I. Candiani and A. Bedeschi, J. Chem. Soc., Chem. Commun., 1994, 0, 597
    DOI: 10.1039/C39940000597

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