A new, short, high-yielding route to 4,5-dihydro-3H-1-benzazepines has been developed based on the rhodium-catalysed hydroformylation of readily available ortho-propenylbenzeneamines; a comparison with the hydroformylation of the corresponding ortho-propenylphenols is made.
D. Anastasiou and W. R. Jackson, J. Chem. Soc., Chem. Commun., 1990, 1205 DOI: 10.1039/C39900001205
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