The condensation of a tris(3-aminopropyl)amine with benzene-1,3-dicarbaldehyde in the presence of AgNO3 produces the dinuclear silver(I) complex of an octa-aza hexa Schiff's base macrobicyclic ligand, which is converted to a unique dinuclear copper(I) hexa Schiff's base cryptate complex by transmetallation.
M. P. Ngwenya, A. E. Martell and J. Reibenspies, J. Chem. Soc., Chem. Commun., 1990, 1207 DOI: 10.1039/C39900001207
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