Issue 3, 1990

Preparation and properties of the mixed trinuclear molybdenum–tungsten cluster ‘aqua ion’; [WMo23-O)(µ2-O)3(OH2)9]4+

Abstract

Reaction of K2[MoCl6](or MoCl4) with K2[WCl6] in HCI (2 M) at 80 °C for 1 h has led to the isolation and characterisation of the first hetero Mo–W trinuclear cluster ‘qua ion’; [WMo23-O)(µ2-O)3(OH2)9]4+; subsequent solution studies have shown that both redox properties and water substitution rates at the two molybdenum centres are significantly influenced by the presence of the remote tungsten atom.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 274-276

Preparation and properties of the mixed trinuclear molybdenum–tungsten cluster ‘aqua ion’; [WMo23-O)(µ2-O)3(OH2)9]4+

A. Patel and D. T. Richens, J. Chem. Soc., Chem. Commun., 1990, 274 DOI: 10.1039/C39900000274

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